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Summary CIE AS Chemistry 9701 Table of All Organic Reactions R74,35   Add to cart

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Summary CIE AS Chemistry 9701 Table of All Organic Reactions

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Extensively and thoroughly organised list of all organic reactions required in the latest CIE AS Chemistry (9701) syllabus. A must-have revision tool that helped me gain an A* in Chemistry in the final A Levels massively.

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  • As organic chemistry chapters
  • May 22, 2023
  • 6
  • 2020/2021
  • Summary
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Alkanes


Reaction Reagent(s) Organic product(s) Other product(s) Conditions Observations/Notes

-Cl2: pale-green to
colourless
-Br2: orange-red to
colourless
-Products vary, eg. more
Free radical substitution Halogenoalkanes Hydrogen halides CHCl3 & CCl4 if Cl2 in
(Initiation, Propagation, Halogens (+ Alkanes x2 substrate (+ Halogens) -UV light excess
Termination) alkane length) -Cl2 and alkanes with
double the C chain
length of substrate
alkane can also be
formed
-TEST: Alkenes
decolourise immediately
in the dark

Combustion O2 CO2 H2O -Plentiful O2 -Produces CO under
limited combustion

Smaller alkenes (+ -No O2 -Higher temperature,
Cracking alkanes) (H2) -Heat proportion of alkenes +
-Al2O3 cat.


Alkenes


-conc. H2SO4/H3PO4 cat.
H2O Alcohols -Heat -Zeitsev’s Rule
-Pressure
-Steam used

Electrophilic addition Halogen Dihalogenoalkanes

-Ni/Pt/Pd cat.
H2 Alkanes -Heat
-H2 dry

Hydrogen halides Halogenoalkanes -Markovnikov’s Rule

, -Purple to colourless
-Cold -Brown if acid present
Alkandiols -Dilute -TEST: Alkanes do not
(H2O needed = reagent) -Acidic change colour
Oxidation KMnO4

-CO2 H2O -Hot -CO2: 2H
-Carboxylic acids -Concentrated -Carboxylic Acids: 1H + 1
-Ketones -Acidic alkyl
-Ketones: 2 alkyls

Free radical addition Polymer alkanes -Heat
polymerisation -Pressure
-Catalyst



Halogenoalkanes


Reaction Reagent(s) Organic product(s) Other product(s) Conditions Observations/Notes

-Reflux -Faster than hydrolysis
Hydroxides -Heat due to OH full formal -
Alcohol -Aqueous charge

H2O -Reflux

Nucleophilic substitution -Reflux
(SN2: 1o, SN1: 3o) Cyanides Nitriles Halides -Heat
-Excess cyanide
-Alcoholic

-Reflux
-Heat
NH3 1o amines -Excess NH3
-Alcoholic
-Pressure

-Reflux
Elimination Hydroxides Alkenes H2O + Halides -Heat -Zeitsev’s Rule
-Alcoholic

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